Improvement of photo-stability of LLDPE-based nanocomposites

LLDPE-based nanocomposites undergo faster photo-oxidation than the unfilled matrix and the extent of their physical properties deterioration, namely elongation at break and tensile strength, is dependent on the organo-nanoclay loading. The observed acceleration is not due to faster photo-oxidation but rather due to a reduction of the oxidation induction time. The presence in the organoclays of trace amounts of metal ions may be promoting catalytic photodegradation. While UV absorbers provide useful protection, use of a metal deactivator has been found to greatly enhance the photo-stability of the LLDPE-based nanocomposites. Combinations of a metal deactivator and UV absorber yield synergistic effects.     

Synthesis of peptides containing 1,2,3,4-tetrahydroquinoline-2-carboxylic acid. Part 3. Cyclization of dipeptides and amides with acetic anhydride

Treatment of protected dipeptides containing 1,2,3,4-tetrahydroquinoline-2-carboxylic acid with acetic anhydride affords only 1H,3H,5H-oxazolo[3,4-a]quinolin-3-one derivatives. The formation of a-acylaminomethylketones, arising from the competitive Dakin-West reaction, was generally observed when the cyclization procedure was extended to some amides of the cyclic imino acid. The preferential stabilization of one of two probable mesoionic intermediates seems to determine the preferred pathway.     

A convenient one-pot procedure for the selective reduction of ketones in the presence of aldehydes

The title process has been accomplished by a three-step sequence involving protection of aldehyde as the imine, $\text{in situ}$ reduction of ketone with lithium tri-$\text{tert}$-butoxyaluminohydride, and regeneration of aldehyde on hydrolytic work-up.     

ICP-AES法测定内蒙古地区六种沙生木本植物中金属元素

采用ICP-AES法分别对内蒙古地区梭梭、小叶锦鸡儿、沙冬青、红柳、沙枣和沙柳等六种沙生木本植物中金属元素进行了测定和分析。该方法的加标回收率为94.98％～120.25％,RSD＜3.4％,具有良好的准确度和精密度。结果表明,常量元素Ca,K,Mg,Na,Al及植物生命活动所必需的微量元素Fe,Mn,Cu,Zn在六种沙生木本植物中表现为不同的含量顺序,且Fe,Mn,Cu,Zn四种元素的含量均低于陆生高等植物的平均含量。该测定结果为改善西部地区生态环境,选择优良防风固沙树种提供可靠的数据和理论依据。     

Exact Solution of the Wave‐Resistance Problem for a Submerged Cylinder. I. Linearized Theory

. We consider the problem of finding a holomorphic function in a strip with a cut ${\cal A}= \{(x,y) : \, x\in\RE,\,\,0 satisfying some prescribed linear conditions on the boundary. The problem has a one‐parameter family of solutions in the class of sectionally holomorphic functions in ?, vanishing for $|x|\to\infty. We consider the problem of finding a holomorphic function in a strip with a cut satisfying some prescribed linear conditions on the boundary. The problem has a one‐parameter family of solutions in the class of sectionally holomorphic functions in ?, vanishing for . A special solution can be selected by fixing the value of the circulation around the cut. The problem is obtained by linearization of the equations of the wave‐resistance problem for a “slender” cylinder submerged in a heavy fluid and moving at uniform speed in the direction orthogonal to its generators. The results obtained, besides their own interest, are a crucial step for the resolution of the non‐linear problem. (Accepted October 14, 1998)     

Ortho-para H₂ conversion by proton exchange at low temperature: an accurate quantum mechanical study

We report extensive, accurate fully quantum, time-independent calculations of cross sections at low collision energies, and rate coefficients at low temperatures for the H? + H?(v = 0, j) → H? + H?(v = 0, j') reaction. Different transitions are considered, especially the ortho-para conversion (j = 1 → j' = 0) which is of key importance in astrophysics. This conversion process appears to be very efficient and dominant at low temperature, with a rate coefficient of 4.15 × 10?1? cm3 molecule?1 s?1 at 10 K. The quantum mechanical results are also compared with statistical quantum predictions and the reaction is found to be statistical in the low temperature regime (T < 100 K).     

On cascade decays of squarks at the LHC in NLO QCD

In this paper we present an analysis at NLO QCD of the contribution from squark-squark production to the experimental signature $2j+l^{+}l^{-}+ \displaystyle{\not}E_T (+X)$ with opposite-sign same flavor leptons, taking into account decays and experimental cuts. We consider the case in which one squark decays directly into the lightest neutralino $\tilde{\chi}^{0} _{1}$ and the other one into the second lightest neutralino and subsequently into $l^{+}l^{-} \tilde{\chi}^{0} _{1}$ via an intermediate slepton. On the one hand we study the effects of the NLO corrections on invariant mass distributions which can be used for future parameter determination. On the other hand we analyze the impact on predictions for cut-and-count searches using the given experimental signature.